Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen

Authors :: Jin-Hong Lin
Sheng-Hua Zhou
Weiguo Cao
Gang Zhao
Ji-Chang Xiao
Source :: RSC Advances. 6:60080-60083
Publication Year :: 2016
Publisher :: Royal Society of Chemistry (RSC), 2016.
Abstract: The hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by a zinc/viologen system is described. Interestingly, no iodoperfluoroalkylation product was observed without the presence of a radical H-donor.

Subjects :: chemistry
010405 organic chemistry
General Chemical Engineering
medicine
chemistry.chemical_element
Viologen
General Chemistry
Zinc
010402 general chemistry
Photochemistry
01 natural sciences
0104 chemical sciences
medicine.drug

Tools