Ammoniation reactions of cis- and trans-[Co(en)2XY]n+ complexes in liquid ammonia, related to the Bailar inversion reaction

Authors :: Hendrikus J. Gamelkoorn
Sijbe Balt
Source :: Inorganic Chemistry. 24:3347-3351
Publication Year :: 1985
Publisher :: American Chemical Society (ACS), 1985.
Abstract: Etude des reactions d'ammoniation des complexes du titre ou X, Y=Cl − , Br − , DMSO, DMT ou X et Y sont des coordinats substitues rapidement. Spectres RMN des produits. Le taux de substitution semble dependre de la nature du coordinat X ou Y le plus fortement lie

Subjects :: Inorganic Chemistry
chemistry.chemical_compound
Ammonia
chemistry
Stereochemistry
Diamine
Liquid ammonia
Sulfoxide
Ethylenediamine
Physical and Theoretical Chemistry
Medicinal chemistry
Cis–trans isomerism
Catalysis

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