Back to Search Start Over

ChemInform Abstract: B-(3,3-Difluoroallyl)diisopinocampheylborane for the Enantioselective Fluoroallylboration of Aldehydes

Authors :
Agnieszka Tafelska-Kaczmarek
P. Veeraraghavan Ramachandran
Anamitra Chatterjee
Source :
ChemInform. 44
Publication Year :
2013
Publisher :
Wiley, 2013.

Abstract

Treatment of difluoroallene (I) with HB(Ipc)2 provides the allylborane (II) whose reaction with various aldehydes allows highly enantioselective access to 2,2-difluorinated homoallylic alcohols.

Details

ISSN :
09317597
Volume :
44
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........65834500c0d48621403b78da76399ef1
Full Text :
https://doi.org/10.1002/chin.201306036