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Polar and radical bicyclizations of cyclo-oct-3-en-1-yl hydroperoxide to afford 2-functionalised-8,9-dioxabicyclo[5.2.1]decanes
- Source :
- Tetrahedron Letters. 31:5513-5516
- Publication Year :
- 1990
- Publisher :
- Elsevier BV, 1990.
-
Abstract
- 8,9-Dioxabicyclo[5.2.1]decanes with bromomercurio, hydroxy, bromo, iodo, and oxo substituents at the 2-position have been prepared from cyclo-oct-3-en-1-yl hydroperoxide; the reactions include extensions of cycloperoxyiodination and of peroxyl radical cyclization to the formation of bicyclic peroxides.
Details
- ISSN :
- 00404039
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........657466b20af3568fa5e2d33206ebbfda