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On the palladium catalyzed reaction of methallyl-1,1-diacetate with cyclic β-ketoesters. Intervention of hidden mechanisms
- Source :
- Tetrahedron Letters. 33:1403-1406
- Publication Year :
- 1992
- Publisher :
- Elsevier BV, 1992.
-
Abstract
- Palladium(0) catalysis in the title reaction causes the release of methacrolein which competes effectively with the π-allyl species in product formation, a bicycloannulated derivative, when DBU is used as base.
Details
- ISSN :
- 00404039
- Volume :
- 33
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........6569ff44e32ced6a6dfced64d4dd46f8
- Full Text :
- https://doi.org/10.1016/s0040-4039(00)91632-0