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Kondo effect in oscillating molecules

Authors :
Jernej Mravlje
Anton Ramšak
Source :
physica status solidi (b). 246:994-998
Publication Year :
2009
Publisher :
Wiley, 2009.

Abstract

We consider electronic transport through break-junctions bridged by a single molecule in the Kondo regime. We describe the system by a two-channel Anderson model. We take the tunneling matrix elements to depend on the position of the molecule. It is shown, that if the modulation of the tunneling by displacement is large, the potential confining the molecule to the central position between the leads is softened and the position of the molecule is increasingly susceptible to external perturbations that break the inversion symmetry. In this regime, the molecule is attracted to one of the leads and as a consequence the conductance is small. We argue on semi-classical grounds why the softening occurs and corroborate our findings by numerical examples obtained by Wilson's numerical renormalization group and Schonhammer-Gunnarsson's variational method.

Details

ISSN :
03701972
Volume :
246
Database :
OpenAIRE
Journal :
physica status solidi (b)
Accession number :
edsair.doi...........63ef83431916107439dc1c61e7b19112
Full Text :
https://doi.org/10.1002/pssb.200881565