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Enzyme assisted enantioselective synthesis of the alkaloid (+)-aloperine

Authors :
Giordano Lesma
Bruno Danieli
Daniele Passarella
Alessandra Silvani
Alessio Barilli
Sergio Riva
Francesca Belinghieri
Source :
Tetrahedron: Asymmetry. 15:2921-2925
Publication Year :
2004
Publisher :
Elsevier BV, 2004.

Abstract

The enantioselective synthesis of the lupinine alkaloid (+)-aloperine is described. The synthetic scheme presents three steps that are mediated by enzymes: kinetic resolution, oxidation of a primary alcohol to an aldehyde and oxidation of a secondary alcohol to a ketone.

Details

ISSN :
09574166
Volume :
15
Database :
OpenAIRE
Journal :
Tetrahedron: Asymmetry
Accession number :
edsair.doi...........62660db776d992f8b49a7b6cea94d970
Full Text :
https://doi.org/10.1016/j.tetasy.2004.06.056