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ChemInform Abstract: Samarium Diiodide Promoted Tandem β-Elimination and Cross-Pinacol Coupling: A New Access to 1-Vinyl-1,2-diols with Two Adjacent Quaternary Carbon Centers

Authors :
Ru-Lin Ma
Guo-Qiang Lin
Yun-Hui Zhao
Xing-Wen Sun
Source :
ChemInform. 43
Publication Year :
2012
Publisher :
Wiley, 2012.

Abstract

1,3-Dioxolane substrates rearrange in the presence of excess SmI2 to afford novel 1,2-diol structures as highly functionalized skeletons for natural product syntheses.

Details

ISSN :
09317597
Volume :
43
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........5dc7d1931f347d9ee2e03a93559f2f98
Full Text :
https://doi.org/10.1002/chin.201251071