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Long-range coupling in a mixed-valence diruthenium complexes containing bis-terpyridine ligands of various lengths as bridges

Authors :
Jean-Pierre Launay
Angélique Sour
Jean-Pierre Sauvage
Philippe P. Lainé
Jean-Paul Collin
Source :
J. Chem. Soc., Chem. Commun.. :434-435
Publication Year :
1993
Publisher :
Royal Society of Chemistry (RSC), 1993.

Abstract

Dinuclear ruthenium(II) complexes have been prepared which contain back-to-back bis-terpyridine ligands of various lengths (Ru ⋯ Ru distances between 7 and 20 A) as bridges; significant electronic coupling is observed in mixed-valence states, even for the system with the longest separation.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
J. Chem. Soc., Chem. Commun.
Accession number :
edsair.doi...........5d2e861000d2360dd04822fe53bd1149