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Effect of F and Mg on the Dispersion of Mo/Al2O3 and W/Al2O3
- Source :
- Journal of Catalysis. 139:72-80
- Publication Year :
- 1993
- Publisher :
- Elsevier BV, 1993.
-
Abstract
- Samples containing 8% Mo and l5% W supported on magnesium- and fluoride-modified aluminas were prepared by incipient wetness impregnation and examined in the dried and calcined states using X-ray photoelectron spectroscopy (XPS, ESCA). The presence of fluoride as an additive decreased the dispersion of the Mo and W phases for dried samples. The opposite effect was observed for dried Mg-modified samples. The effects of F and Mg addition largely disappeared when the samples were calcined. The results are interpreted in terms of the interactions between Mo and W species and the basic hydroxyl groups of the alumina.
- Subjects :
- Chemistry
Magnesium
Inorganic chemistry
technology, industry, and agriculture
chemistry.chemical_element
Catalysis
law.invention
chemistry.chemical_compound
X-ray photoelectron spectroscopy
Transition metal
law
Molybdenum
Calcination
Physical and Theoretical Chemistry
Dispersion (chemistry)
Fluoride
Incipient wetness impregnation
Nuclear chemistry
Subjects
Details
- ISSN :
- 00219517
- Volume :
- 139
- Database :
- OpenAIRE
- Journal :
- Journal of Catalysis
- Accession number :
- edsair.doi...........5d26050581e3abc547ae523063fb6c5a