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Exfoliated Nanocomposites of Polyvinyl Acetate-N-Hydroxymethyl Acrylamide and Intercalated Montmorillonite from an Octadecyl Trimethyl Ammonium Bromide Surfactant

Authors :
Guanben Du
Qun Fang
Hui-Wang Cui
Source :
Polymer-Plastics Technology and Engineering. 53:961-968
Publication Year :
2014
Publisher :
Informa UK Limited, 2014.

Abstract

In this study, we introduced N-hydroxymethyl acrylamide and an organic montmorillonite intercalated by an octadecyl trimethyl ammonium bromide surfactant together into the in situ polymerization of polyvinyl acetate to form exfoliated nanocomposites. Wide-angle X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, power-law function equation, Newtonian fluid flow equation, Cross-Williamson model viscous equation, Hooke's law, and Poisson's ratio equation revealed the structures, dispersion, rheology, and static tensile properties. The exfoliated nanocomposites were pseudo-plastic non-Newtonian fluids, presented a good dispersion in water, a great storage stability, and a high static tensile strength at 6.78–8.06 MPa.

Details

ISSN :
15256111 and 03602559
Volume :
53
Database :
OpenAIRE
Journal :
Polymer-Plastics Technology and Engineering
Accession number :
edsair.doi...........5aceeb7212a828724b17b2690afeec3e