Paramagnetic Organocobalt(III) Dithiolate Complex: Crystal Structure and Magnetic Property of [Co(η5-C5Me5)(C3S5)Br]

Authors :: Gen-etsu Matsubayashi
Hiroyuki Mori
Hatsue Tamura
Wasuke Mori
Motohiro Nakano
Source :: Chemistry Letters. 27:729-730
Publication Year :: 1998
Publisher :: The Chemical Society of Japan, 1998.
Abstract: The crystal structure of the paramagnetic, title complex revealed one-dimensional molecular interaction through S–S non-bonded contacts. The complex with the one-electron C3S5 ligand-centered oxidation exhibited a strong antiferromagnetic interaction in the solid state.

Subjects :: Crystallography
Paramagnetism
Chemistry
Solid-state
Antiferromagnetism
Condensed Matter::Strongly Correlated Electrons
General Chemistry
Crystal structure

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