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Synthesis and characterization of diiron ethanedithiolate complexes with monosubstituted phosphine ligands
- Source :
- Journal of Coordination Chemistry. 69:1439-1446
- Publication Year :
- 2016
- Publisher :
- Informa UK Limited, 2016.
-
Abstract
- Reactions of (μ-edt)Fe2(CO)6 (edt = SCH2CH2S) (1) with the monophosphine ligands Ph2PCH2Ph, Ph2PC6H11, Ph2PCH2CH2CH3, or P(2-C4H3O)3 in the presence of Me3NO∙2H2O afforded (μ-edt)Fe2(CO)5L [L = Ph2PCH2Ph, 2; Ph2PC6H11, 3; Ph2PCH2CH2CH3, 4; P(2-C4H3O)3, 5] in 70–88% yields. Complexes 2–5 were characterized by spectroscopy and single crystal X-ray diffraction analysis. The phosphorus of 2–5 is in an apical position of the distorted octahedral geometry of iron.
- Subjects :
- Diffraction
010405 organic chemistry
Phosphorus
Inorganic chemistry
chemistry.chemical_element
010402 general chemistry
01 natural sciences
0104 chemical sciences
Characterization (materials science)
Crystallography
chemistry.chemical_compound
chemistry
X-ray crystallography
Octahedral molecular geometry
Materials Chemistry
Physical and Theoretical Chemistry
Spectroscopy
Single crystal
Phosphine
Subjects
Details
- ISSN :
- 10290389 and 00958972
- Volume :
- 69
- Database :
- OpenAIRE
- Journal :
- Journal of Coordination Chemistry
- Accession number :
- edsair.doi...........5910820391d448b868692d8e8e4928e0