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Nitrogen-doped-carbon-coated SnO2nanoparticles derived from a SnO2@MOF composite as a lithium ion battery anode material
- Source :
- RSC Advances. 7:20062-20067
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- N-Doped-carbon-coated 2–4 nm SnO2 nanoparticles were synthesized via a facile metal–organic framework (MOF) coating process followed by a calcination of the SnO2@MOF composite. The as-prepared SnO2 nanoparticles are well dispersed and coated with a uniform nitrogenous carbon structure, which can effectively prevent volume expansion during discharge and charge processes. Benefiting from the advantages of a synergistic effect of SnO2 nanoparticles and carbon structure, these materials exhibit excellent electrochemical performance. For the optimized material SOC-3, a reversible specific capacity of 1032 mA h g−1 was maintained at 100 mA g−1 after 150 cycles with a coulombic efficiency of 99%. When the current was increased to 500 mA g−1, a capacity of 600 mA h g−1 was still attained.
- Subjects :
- Materials science
General Chemical Engineering
Composite number
chemistry.chemical_element
Nanoparticle
Nanotechnology
02 engineering and technology
General Chemistry
engineering.material
010402 general chemistry
021001 nanoscience & nanotechnology
Electrochemistry
01 natural sciences
0104 chemical sciences
law.invention
Coating
Chemical engineering
chemistry
law
engineering
Carbon coating
Calcination
0210 nano-technology
Carbon
Faraday efficiency
Subjects
Details
- ISSN :
- 20462069
- Volume :
- 7
- Database :
- OpenAIRE
- Journal :
- RSC Advances
- Accession number :
- edsair.doi...........58f9ade564f03dda4c3ae4a55f4cd507
- Full Text :
- https://doi.org/10.1039/c7ra02703f