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Nitrogen-doped-carbon-coated SnO2nanoparticles derived from a SnO2@MOF composite as a lithium ion battery anode material

Authors :
Wei Shi
Peng Cheng
Hao Yang
Fengcai Li
Jia Du
Source :
RSC Advances. 7:20062-20067
Publication Year :
2017
Publisher :
Royal Society of Chemistry (RSC), 2017.

Abstract

N-Doped-carbon-coated 2–4 nm SnO2 nanoparticles were synthesized via a facile metal–organic framework (MOF) coating process followed by a calcination of the SnO2@MOF composite. The as-prepared SnO2 nanoparticles are well dispersed and coated with a uniform nitrogenous carbon structure, which can effectively prevent volume expansion during discharge and charge processes. Benefiting from the advantages of a synergistic effect of SnO2 nanoparticles and carbon structure, these materials exhibit excellent electrochemical performance. For the optimized material SOC-3, a reversible specific capacity of 1032 mA h g−1 was maintained at 100 mA g−1 after 150 cycles with a coulombic efficiency of 99%. When the current was increased to 500 mA g−1, a capacity of 600 mA h g−1 was still attained.

Details

ISSN :
20462069
Volume :
7
Database :
OpenAIRE
Journal :
RSC Advances
Accession number :
edsair.doi...........58f9ade564f03dda4c3ae4a55f4cd507
Full Text :
https://doi.org/10.1039/c7ra02703f