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Electron-deficient molecules: photophysical, electrochemical, and thermal investigations of naphtho[2,3-f]quinoxaline-7,12-dione derivatives
- Source :
- Chemistry of Heterocyclic Compounds. 52:110-115
- Publication Year :
- 2016
- Publisher :
- Springer Science and Business Media LLC, 2016.
-
Abstract
- In this work, we have prepared a series of 2,3-disubstituted naphtho[2,3-f]quinoxaline-7,12-dione derivatives by condensing 1,2-diaminoanthraquinone and various benzil compounds in glacial acetic acid with excellent yield and fully characterized. Optical properties of the synthesized compounds were studied in solvents of varying polarity and thin solid film. Electrochemical properties of the compounds were studied by the cyclic voltammetry. The ionization potentials (HOMO) and electron affinity (LUMO) were found to be in the range of −6.364 to −6.644 eV and −3.247 to −3.511 eV, respectively. Thermal investigations were carried out by thermogravimetric analysis and differential scanning calorimetry.
- Subjects :
- Thermogravimetric analysis
010405 organic chemistry
Chemistry
Organic Chemistry
010402 general chemistry
Photochemistry
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
Differential scanning calorimetry
Quinoxaline
Electron affinity (data page)
Molecule
Benzil
Cyclic voltammetry
HOMO/LUMO
Subjects
Details
- ISSN :
- 15738353 and 00093122
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Chemistry of Heterocyclic Compounds
- Accession number :
- edsair.doi...........5760d78df4b1663057ce3f0a819ea5d6