ChemInform Abstract: Probing the Origin of Carboxylate Migration Selectivity in Rh2(II)-Catalyzed N-Heterocycle Formation from Trisubstituted Styryl Azides

Authors :: Tom G. Driver
Fei Zhou
Chen Kong
Naijing Su
Navendu Jana
Source :: ChemInform. 46
Publication Year :: 2015
Publisher :: Wiley, 2015.
Abstract: Exposure of trisubstituted styryl azides (I), (IV), (VI), and (VIII) to Rh2(II)-carboxylate catalyst triggers a tandem 4π-electron-5-atom electrocyclization-migration reaction.

Subjects :: inorganic chemicals
chemistry.chemical_compound
chemistry
Tandem
Heterocycle formation
General Medicine
Carboxylate
Selectivity
Medicinal chemistry
Catalysis

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