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Near-equiatomic high-entropy decagonal quasicrystal in Al20Si20Mn20Fe20Ga20

Authors :
Zhanbing He
Liangqun Zhao
Tulai Sun
Ding-hao Miao
Ruixuan Li
Tiantian Zhang
Yong Zhang
Haikun Ma
Zhi-Yi Hu
Hua Li
He Tian
Source :
Science China Materials. 64:440-447
Publication Year :
2020
Publisher :
Springer Science and Business Media LLC, 2020.

Abstract

High-entropy alloys (HEAs) contain multiple principal alloying elements, but usually with simple crystal structures. Quasicrystals are structurally complex phases, but are generally dominated by only one element. However, near-equiatomic high-entropy quasicrystals have rarely been reported because they are difficult to prepare experimentally and predict theoretically. Therefore, the preparation and crystal structures of near-equiatomic high-entropy quasicrystals have drawn much interest. We report a quinary decagonal quasicrystal (DQC) with near-equiatomic alloying elements in Al20Si20Mn20Fe20Ga20 melt-spun ribbons, which is the first to our knowledge. Meanwhile, the structural features of the DQC are characterized in detail. The configurational entropy of both the alloy and DQC satisfies the entropy-based criterion for HEAs, suggesting a high-entropy DQC. Our findings provide a new strategy to develop high-entropy quasicrystals.

Details

ISSN :
21994501 and 20958226
Volume :
64
Database :
OpenAIRE
Journal :
Science China Materials
Accession number :
edsair.doi...........5743235860657dc63fa80bc8236cab77
Full Text :
https://doi.org/10.1007/s40843-020-1441-3