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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2N3,O4)cadmiumN,N-dimethylformamide disolvate
- Source :
- Acta Crystallographica Section E Structure Reports Online. 67:m1870-m1871
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography (IUCr), 2011.
-
Abstract
- In the title complex, [Cd(C8H9N2O4)2(H2O)2]·2C3H7NO, the six-coordinate CdII ion is in a slightly distorted octa­hedral environment, defined by two O atoms from two coordinated water mol­ecules and two carboxyl­ate O atoms and two N atoms from two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands. In the crystal, complex mol­ecules and dimethyl­formamide solvent mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a two-dimensional supra­molecular structure. The propyl groups of the ligands are disordered over two conformations with refined occupancies of 0.680 (7) and 0.320 (7).
Details
- ISSN :
- 16005368
- Volume :
- 67
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........56e0034e3e165b3dadc89efaba317c00
- Full Text :
- https://doi.org/10.1107/s1600536811050264