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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2N3,O4)cadmiumN,N-dimethylformamide disolvate

Authors :
Wen-Dong Song
Dong-Liang Miao
Shao-Wei Tong
Shi-Jie Li
Jing-Bo An
Source :
Acta Crystallographica Section E Structure Reports Online. 67:m1870-m1871
Publication Year :
2011
Publisher :
International Union of Crystallography (IUCr), 2011.

Abstract

In the title complex, [Cd(C8H9N2O4)2(H2O)2]·2C3H7NO, the six-coordinate CdII ion is in a slightly distorted octa­hedral environment, defined by two O atoms from two coordinated water mol­ecules and two carboxyl­ate O atoms and two N atoms from two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands. In the crystal, complex mol­ecules and dimethyl­formamide solvent mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a two-dimensional supra­molecular structure. The propyl groups of the ligands are disordered over two conformations with refined occupancies of 0.680 (7) and 0.320 (7).

Details

ISSN :
16005368
Volume :
67
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........56e0034e3e165b3dadc89efaba317c00
Full Text :
https://doi.org/10.1107/s1600536811050264