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Varying the Alkali-Metal Radii in (KxRb1–x)n[GaH2]n (0 ≤ x ≤ 1) Reorients a Stable Polyethylene-Structured [GaH2]nn– Anionic Chain

Authors :
Henrik Fahlquist
Dag Noréus
Magnus H. Sørby
Source :
Inorganic Chemistry. 52:4771-4773
Publication Year :
2013
Publisher :
American Chemical Society (ACS), 2013.

Abstract

The stability of a negatively chargedpolyethylene-structured [GaH2]nn−cluster ion was inves-tigated by varying the K+/Rb+ratio in (KxRb1−x)n[GaH2]n(0≤x≤1). Neutron, X-ray, and IR spectroscopies wer ...

Details

ISSN :
1520510X and 00201669
Volume :
52
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........569012354448c9d97255229dc7f424c0
Full Text :
https://doi.org/10.1021/ic400224a