Back to Search
Start Over
Synthesis of N1,N1,N3,N3-tetrasubstituted diethylenetriamines
- Source :
- Russian Chemical Bulletin. 67:840-843
- Publication Year :
- 2018
- Publisher :
- Springer Science and Business Media LLC, 2018.
-
Abstract
- Preparative procedures for the synthesis of N1,N1,N3,N3-tetrasubstituted diethylenetriamines via aminoalkylation of N,N-disubstituted ethylenediamines with N,N-disubstituted 2-chloroethylamines were developed. Aminoalkylation of N,N-dimethylethylenediamine under heating gave simultaneously secondary N1,N1,N3,N3-tetrasubstituted diethylenetriamines and quaternary ammonium salts, N-(2-aminoethyl)-N-(2-dialkylaminoethyl)-N,N-dimethylammonium chlorides. Structures of the synthesized compounds were established by IR spectroscopy, 1H and 13C NMR spectroscopy, and electrospray ionization mass spectrometry.
Details
- ISSN :
- 15739171 and 10665285
- Volume :
- 67
- Database :
- OpenAIRE
- Journal :
- Russian Chemical Bulletin
- Accession number :
- edsair.doi...........54afa17f711e2c87a9a13be97fb9f5f4
- Full Text :
- https://doi.org/10.1007/s11172-018-2147-y