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Synthesis of N1,N1,N3,N3-tetrasubstituted diethylenetriamines

Authors :
N. Yu. Borisova
E. Ya. Borisova
D. Q. Hoang
V. K. Lesnikov
A. V. Krylov
Source :
Russian Chemical Bulletin. 67:840-843
Publication Year :
2018
Publisher :
Springer Science and Business Media LLC, 2018.

Abstract

Preparative procedures for the synthesis of N1,N1,N3,N3-tetrasubstituted diethylenetriamines via aminoalkylation of N,N-disubstituted ethylenediamines with N,N-disubstituted 2-chloroethylamines were developed. Aminoalkylation of N,N-dimethylethylenediamine under heating gave simultaneously secondary N1,N1,N3,N3-tetrasubstituted diethylenetriamines and quaternary ammonium salts, N-(2-aminoethyl)-N-(2-dialkylaminoethyl)-N,N-dimethylammonium chlorides. Structures of the synthesized compounds were established by IR spectroscopy, 1H and 13C NMR spectroscopy, and electrospray ionization mass spectrometry.

Details

ISSN :
15739171 and 10665285
Volume :
67
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........54afa17f711e2c87a9a13be97fb9f5f4
Full Text :
https://doi.org/10.1007/s11172-018-2147-y