Electron-Transfer-Induced Diels-Alder Reactions of Indole and Exocyclic Dienes: Synthesis and Quantum-Chemical Studies

Authors :: Siegfried Blechert
Olaf Wiest
Udo Haberl
Eberhard Steckhan
Source :: Chemistry - A European Journal. 5:2859-2865
Publication Year :: 1999
Publisher :: Wiley, 1999.
Abstract: Regio- and stereoselectivities of radical-cation Diels–Alder reactions (see equation) can be explained and predicted by quantum-chemical calculations. The cycloadditions between indole and exocyclic dienes are catalyzed by photoinduced electron transfer.

Subjects :: Indole test
Quantum chemical
Chemistry
Organic Chemistry
General Chemistry
Photochemistry
Catalysis
Photoinduced electron transfer
Electron transfer
Computational chemistry
Ab initio quantum chemistry methods
Diels alder
Density functional theory

ISSN :: 15213765 and 09476539
Volume :: 5
Database :: OpenAIRE
Journal :: Chemistry - A European Journal
Accession number :: edsair.doi...........54a578a91c652ca06be8cde95a7581b1
Full Text :: https://doi.org/10.1002/(sici)1521-3765(19991001)5:10<2859::aid-chem2859>3.0.co;2-r

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