AlPO4-supported rhodium catalysts. VIII. Gas-phase adsorption of arenes by gas-chromatography

Authors :: Diego Luna
J. M. Campelo
Felipa M. Bautista
José María Marinas
Angel Garcia
Source :: Reaction Kinetics and Catalysis Letters. 31:327-332
Publication Year :: 1986
Publisher :: Springer Science and Business Media LLC, 1986.
Abstract: The adsorption of normal and α-methylated series arenes on rhodium supported on two kinds of AlPO4 has been studied by using a gas-solid chromatographic technique. The adsorption process was exothermic (δHads 0) the relative adsorption constants being fitted to the Pavelich-Taft equation in which the electrical effect of the alkyl substituent is the main influence.

Subjects :: chemistry.chemical_classification
Exothermic reaction
Inorganic chemistry
Substituent
chemistry.chemical_element
Catalysis
Gas phase
Rhodium
chemistry.chemical_compound
Adsorption
chemistry
Gas chromatography
Physical and Theoretical Chemistry
Alkyl

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