Differences in the Solid-State Structures of Single-Site and Ziegler−Natta Linear Low-Density Polyethylenes As Revealed by Molecular Dynamics Simulation

Molecular dynamics (MD) simulations were carried out to study the solid-state structures of single-site (ss) and Ziegler−Natta (ZN) linear low-density polyethylenes (LLDPE) at a temperature slightly below their melting temperatures. The two bulk state models, used to represent the polymers, possessed the same average branch content (10 hexyl branches per 1000 backbone carbons) but with different degrees of interchain branch distribution homogeneity. Both models were first equilibrated at 463 K (i.e., 190 °C) for several nanoseconds, and the resultant structures, which were found to be representative of the corresponding liquid-state structures, were then used as the initial structures for the subsequent quenching process. The quenching temperature was 373 K (i.e., 100 °C), and the structures were then equilibrated at the same temperature for a period of about 10 ns. The structures of the two polymers formed after the low-temperature equilibrations were considerably different. In particular, the ZN-LLDPE m...