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Characterization and evaluation of antioxidation of lignin from bamboo powder using a formic acid-catalyzed ethanol organosolv process
- Source :
- January 2019. 18:59-65
- Publication Year :
- 2019
- Publisher :
- TAPPI, 2019.
-
Abstract
- The antioxidant activity of lignin for producing biochemicals has attracted attention. In this paper, a separation method for lignin is proposed, with high-yield and high-antioxidant activity by using a formic acid-catalyzed subcritical ethanol process. The formic acid-catalyzed ethanol lignin (EOL/FA) and ethanol organosolv lignin (EOL) were first prepared using a high-pressure autoclave at different formic acid dosages. Then, the antioxidant activity and the structural and thermal properties of EOL/FA, EOL, alkali lignin, and sodium lignosulfonate were analyzed using antioxidant analysis, Fourier transform infrared (FTIR) spectroscopy analysis, and thermogravimetric analysis (TGA). The phenolic hydroxyl content of the four lignins was also determined by the Folin–Ciocalteau colorimetric method. Results showed EOL/FA had a higher radical scavenging ability and higher total phenolic hydroxyl content than industrial lignin. It indicated that the formic acid-catalyzed subcritical ethanol process was effective for enhancing the antioxidant activity of lignin.
- Subjects :
- Bamboo
Formic acid
General Chemical Engineering
Organosolv
macromolecular substances
02 engineering and technology
010402 general chemistry
complex mixtures
01 natural sciences
Catalysis
chemistry.chemical_compound
Media Technology
Lignin
Organic chemistry
General Materials Science
Ethanol
Chemistry
Mechanical Engineering
technology, industry, and agriculture
food and beverages
General Chemistry
021001 nanoscience & nanotechnology
humanities
0104 chemical sciences
Characterization (materials science)
Scientific method
0210 nano-technology
Subjects
Details
- ISSN :
- 07341415
- Volume :
- 18
- Database :
- OpenAIRE
- Journal :
- January 2019
- Accession number :
- edsair.doi...........5223bba8488c99697eb7afc6c237c1e3