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Laser-induced solution combustion of nano-Y 2.96 Al 5 O 12 :0.04Ce phosphors and their fluorescent properties for white light conversion
- Source :
- Journal of Alloys and Compounds. 711:42-50
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- White light emission from blue light-emitting diodes (blue-LED) was generated using phosphor. Yttrium nitrate and aluminum nitrate phosphor doped with cerium nitrate (activator) and mixed with urea (fuel) were synthesized by a novel technique that uses continuous wave–CO2 laser-induced solution combustion synthesis (LISCS, 40 W). The annealing temperature to enhance crystallinity of particles at 1050 °C was achieved for 5 h. The crystallinity, structure, chemical composition, electroluminescence properties, and chromaticity of the powder phosphor samples with the composition Y(3−x) Al5O12:xCe3+ (x = 0.04) are reported in this study. All samples were investigated using Brunauer–Emmett–Teller method, X-ray diffraction, field emission-scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, electroluminescence and standard CIE 1931 chromaticity analysis. By controlling the composition and chemical structure of Y2.96Al5O12:0.04Ce3+ (YAG:Ce+3) mixed with epoxy, white light with a broadband luminescence spectrum, high color rendering index, and tunable correlated color temperature exhibits and offer cool white LED. Results reveal that the phosphor prepared using the novel technique (such as LISCS) produces excellent crystal phase and morphology, as well as better luminescence properties than the phosphor synthesized by using the traditional microwave technique.
- Subjects :
- Materials science
Mechanical Engineering
Metals and Alloys
Analytical chemistry
Energy-dispersive X-ray spectroscopy
Phosphor
02 engineering and technology
Color temperature
Electroluminescence
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Crystallinity
Mechanics of Materials
Materials Chemistry
Chromaticity
Fourier transform infrared spectroscopy
0210 nano-technology
Luminescence
Subjects
Details
- ISSN :
- 09258388
- Volume :
- 711
- Database :
- OpenAIRE
- Journal :
- Journal of Alloys and Compounds
- Accession number :
- edsair.doi...........51de3387c35122b61cc92a716fbe8503
- Full Text :
- https://doi.org/10.1016/j.jallcom.2017.03.359