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Polymerization of acrylonitrile initiated by a manganese(III) acetate glycerol redox system
- Source :
- Journal of Polymer Science: Polymer Chemistry Edition. 21:407-413
- Publication Year :
- 1983
- Publisher :
- Wiley, 1983.
-
Abstract
- The kinetics of polymerization of acrylonitrile(AN) initiated by manganese(III) acetate in the presence of glycerol was investigated in the temperature range of 30–40°C. The effect of varying the concentrations of glycerol, sulfuric acid, acetic acid, metal ion, and monomer on the rate was studied. A suitable reaction scheme and rate expression have been proposed. Termination was mutual and was caused by the combination of two growing polymer radicals.
Details
- ISSN :
- 15429369 and 03606376
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Journal of Polymer Science: Polymer Chemistry Edition
- Accession number :
- edsair.doi...........50dc184463ba2f5a134dbcda1294b757