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Quantum antiferromagnet bluebellite comprising a maple-leaf lattice made of spin- 1/2Cu2+ ions
- Source :
- Physical Review B. 104
- Publication Year :
- 2021
- Publisher :
- American Physical Society (APS), 2021.
-
Abstract
- Spin-1/2 maple leaf lattice antiferromagnets are expected to show interesting phenomena originating from frustration effects and quantum fluctuations. We report the hydrothermal synthesis of a powder sample of bluebellite Cu$_6$IO$_3$(OH)$_{10}$Cl as a first potential candidate. Magnetization and heat capacity measurements reveal moderate frustration with a Curie-Weiss temperature of $-35$ K, and a magnetic transition at $T_N$ = 17 K. Surprisingly, the magnetic susceptibility and heat capacity above $T_N$ are well reproduced by the Bonner-Fisher model, which suggests that a one-dimensional spin correlation with a magnetic interaction of 25 K occurs in the apparently two-dimensional lattice. This emergent one-dimensionality cannot be explained by orbital ordering or dimensional reduction due to geometrical frustration. We believe that there is an unknown mechanism to cause one-dimensionality in the spin-1/2 maple leaf lattice antiferromagnet.
Details
- ISSN :
- 24699969 and 24699950
- Volume :
- 104
- Database :
- OpenAIRE
- Journal :
- Physical Review B
- Accession number :
- edsair.doi...........50327431f8db64b99674d29ba0d84263