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ChemInform Abstract: The Generation of α-Trimethylsiloxy-o-quinodimethanes Induced by One-Electron Reduction to o-Acylbenzyltributylstannanes
- Source :
- ChemInform. 28
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- o -Tributylstannylmethyl benzaldehyde reacts with Zn in the presence of TMSCl and 2,6 lutidine at room temperature to give α-trimethylsiloxy- o -quinodimethane, which is trapped with dienophiles to afford cycloadducts in good to high yields.
Details
- ISSN :
- 09317597
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........50048e7f7b17e9f7be1b39db5b69de93
- Full Text :
- https://doi.org/10.1002/chin.199716059