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Merging the AuCu3- and BaAl4-based structure motifs: flux-assisted synthesis, crystal, and electronic structure of Ca2Pt7XP4−δ phosphide platinides (X = Al, Ti, and Zn)

Authors :
Anastasiya Yu. Makhaneva
Elena Yu. Zakharova
Sergey N. Nesterenko
Konstantin A. Lyssenko
Alexey N. Kuznetsov
Source :
Dalton Transactions. 51:18583-18592
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Three quaternary phosphide platinides, Ca2Pt7AlP3.00(4), Ca2Pt7TiP3.24(4), and Ca2Pt7ZnP2.78(2), were synthesized by a high-temperature technique using lead as a flux.

Subjects

Subjects :
Inorganic Chemistry

Details

ISSN :
14779234 and 14779226
Volume :
51
Database :
OpenAIRE
Journal :
Dalton Transactions
Accession number :
edsair.doi...........4fac43d74472479bbbdbd99fe7844232
Full Text :
https://doi.org/10.1039/d2dt03367d