A peculiar heterotrimetallic MnII–CoII–NiII complex: Synthesis, crystal structure and magnetic properties

Authors :: Gong-Feng Xu
Qing-Lun Wang
Bin Liu
Shi-Ping Yan
Hai-Bin Song
Dai-Zheng Liao
Source :: Inorganic Chemistry Communications. 11:714-716
Publication Year :: 2008
Publisher :: Elsevier BV, 2008.
Abstract: The first complex [Mn(H2O)6][NiCo(TTHA)(H2O)2] · 4H2O 1 (TTHA6− = triethylenetetraminehexaacetate) containing MnII–CoII–NiII three different 3d metal ions is synthesized and magnetic measurement suggests that ferromagnetic interactions occur between Ni2+ ions and rarely found low-spin Co2+ ions.

Subjects :: Inorganic Chemistry
Crystallography
Materials science
Ferromagnetism
Metal ions in aqueous solution
Materials Chemistry
Crystal structure
Physical and Theoretical Chemistry
Triethylenetetraminehexaacetic acid
Ion

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