Infrared Spectroscopy of Dust in the Diffuse Interstellar Medium toward Cygnus OB2 No. 12

Observations made with the short-wavelength spectrometer of the Infrared Space Observatory are used to investigate the composition of interstellar dust in the line of sight to Cygnus OB2 No. 12, commonly taken as representative of the diffuse (low-density) interstellar medium. Results are compared with data for the Galactic center source Sgr A*. Nondetections of the 3.0 and 4.27 μm features of H2O and CO2 ices in Cyg OB2 No. 12 confirm the absence of dense molecular material in this line of sight, whereas the presence of these features in Sgr A* indicates that molecular clouds may contribute as much as 10 mag of visual extinction toward the Galactic center. The spectrum of Cyg OB2 No. 12 is dominated by the well-known 9.7 μm silicate feature; detection of a shallow feature near 2.75 μm indicates that the silicates are at least partially hydrated, with composition possibly similar to that of terrestrial phyllosilicates such as serpentine or chlorite. However, the 2.75 μm feature is not seen in the Galactic center spectrum, suggesting that silicates in this line of sight are less hydrated or of different composition. The primary spectral signatures of C-rich dust in the diffuse ISM are weak absorptions at 3.4 μm (the aliphatic C=H stretch) and 6.2 μm (the aromatic C=C stretch). We conclude, based on infrared spectroscopy, that the most probable composition of the dust toward Cyg OB2 No. 12 is a mixture of silicates and carbonaceous solids in a volume ratio of approximately 3:2, with the carbonaceous component primarily in an aromatic form such as amorphous carbon.