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ChemInform Abstract: High Pressure Behavior of Mercury Cyanamide HgCN2

Authors :
Wilhelm Klein
Holger Bender
Martin Jansen
Haozhe Liu
Source :
ChemInform. 33
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Using the diamond anvil cell technique, angle-dispersive X-ray diffraction and Raman spectroscopy were employed to study the high pressure behavior of mercury cyanamide. Its decomposition under pressure starts at 1.9 GPa and is not completed even up to 10 GPa. The decomposition product α-Hg transforms to β-Hg during 7–10 GPa, while the C/N residual is not detectable by X-ray diffraction. The zero pressure bulk modulus of mercury cyanamide is estimated as 38.5 GPa.

Details

ISSN :
15222667 and 09317597
Volume :
33
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........4f117ec1c7dba929c121a6484b725a06
Full Text :
https://doi.org/10.1002/chin.200212014