Heteropolymetallic Supramolecular Solid-State Architectures Constructed from Dicyanoaurate Ion, Phen, and 3d Metals

Authors :: Hui-Bo Zhou
Gong-Feng Xu
Dai-Zheng Liao
Yang Guo
Zhan-Quan Liu
Source :: Australian Journal of Chemistry. 59:640
Publication Year :: 2006
Publisher :: CSIRO Publishing, 2006.
Abstract: Two new supramolecular polymeric coordination complexes, {Zn(phen)2[Au2(CN)4](H2O)}·1.5H2O 1 and {Mn(phen)[Au2(CN)4](H2O)}·PriOH 2, have been obtained through a self-assembly process. The three-dimensional supramolecular architectures of compounds 1 and 2 are sustained by aurophilic, hydrogen-bonding, and/or π–π interactions. Gold atoms linked with aurophilic bonds arrange in a pattern not frequently observed.

Subjects :: Crystallography
chemistry.chemical_compound
Chemistry
Ionic liquid
Supramolecular chemistry
Physical chemistry
Density functional theory
General Chemistry
Crystal structure
Self-assembly
Electrochemistry
Quantum chemistry
Macromolecule

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