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Heteropolymetallic Supramolecular Solid-State Architectures Constructed from Dicyanoaurate Ion, Phen, and 3d Metals
- Source :
- Australian Journal of Chemistry. 59:640
- Publication Year :
- 2006
- Publisher :
- CSIRO Publishing, 2006.
-
Abstract
- Two new supramolecular polymeric coordination complexes, {Zn(phen)2[Au2(CN)4](H2O)}·1.5H2O 1 and {Mn(phen)[Au2(CN)4](H2O)}·PriOH 2, have been obtained through a self-assembly process. The three-dimensional supramolecular architectures of compounds 1 and 2 are sustained by aurophilic, hydrogen-bonding, and/or π–π interactions. Gold atoms linked with aurophilic bonds arrange in a pattern not frequently observed.
Details
- ISSN :
- 00049425
- Volume :
- 59
- Database :
- OpenAIRE
- Journal :
- Australian Journal of Chemistry
- Accession number :
- edsair.doi...........4ec1e178c449de52466533071b1d16bc