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Amendment to bertran equation and the weak Fermi resonance characteristic of CS2 in C6H6
- Source :
- Acta Physica Sinica. 58:3538
- Publication Year :
- 2009
- Publisher :
- Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, 2009.
-
Abstract
- The Raman spectra of CS 2 in C 6 H 6 is messured and the Fermi resonance of v 1 —2 v 2 in solution and in pure CS 2 is obvionsly different.The characteristic parameters are calculated by Berttern equation.It was found that with the concentration of CS 2 declining,the ratio of the spectral intensity ( R = I 655 / I 796 ) decreases and the coupling coefficient ( W ) raises, and the other parameters also change correspondingly. The analysis shows that dissipation coefficient of v 0 1 of CS 2 is affected by the concentration of C 6 H 6 . Asymmetric frequency shift of v 0 1 and 2 v 0 2 are observed in experiment,which is explained by amending the Bertran theory. This report has reference value for the molecule spectrum certification and the understanding and use of Fermi resonance theory.
Details
- ISSN :
- 10003290
- Volume :
- 58
- Database :
- OpenAIRE
- Journal :
- Acta Physica Sinica
- Accession number :
- edsair.doi...........4e801f572cf404e0a9d36ef8d674ffdf