Back to Search Start Over

Amendment to bertran equation and the weak Fermi resonance characteristic of CS2 in C6H6

Authors :
Zuo Jian
Jiang Yong-Heng
Ouyang Shun-Li
Li Zuo-Wei
Gao Shu-Qin
LU Guo-Hui
Cao Biao
Source :
Acta Physica Sinica. 58:3538
Publication Year :
2009
Publisher :
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, 2009.

Abstract

The Raman spectra of CS 2 in C 6 H 6 is messured and the Fermi resonance of v 1 —2 v 2 in solution and in pure CS 2 is obvionsly different.The characteristic parameters are calculated by Berttern equation.It was found that with the concentration of CS 2 declining,the ratio of the spectral intensity ( R = I 655 / I 796 ) decreases and the coupling coefficient ( W ) raises, and the other parameters also change correspondingly. The analysis shows that dissipation coefficient of v 0 1 of CS 2 is affected by the concentration of C 6 H 6 . Asymmetric frequency shift of v 0 1 and 2 v 0 2 are observed in experiment,which is explained by amending the Bertran theory. This report has reference value for the molecule spectrum certification and the understanding and use of Fermi resonance theory.

Details

ISSN :
10003290
Volume :
58
Database :
OpenAIRE
Journal :
Acta Physica Sinica
Accession number :
edsair.doi...........4e801f572cf404e0a9d36ef8d674ffdf