Unprecedented Coordination Mode Variation of Group 13 Metal–Alkyl Compounds Derived from Methyl Thiosalicylate

Authors :: Ewa Tratkiewicz
Tomasz Kopeć
Janusz Lewiński
Wojciech Bury
Janusz Lipkowski
Iwona Justyniak
Source :: European Journal of Inorganic Chemistry. 2005:3414-3417
Publication Year :: 2005
Publisher :: Wiley, 2005.
Abstract: The X-ray structure analysis of the alkylaluminum and -indium compounds derived from methyl thiosalicylate, Me2Al(SC6H4-2-CO2Me) and [Me2In(µ-SC6H4-2-CO2Me)]2, revealed that the intermolecular S···C(π) interaction between the Al–S thiolate units and the ester π-surface can effectively compete with the hypercoordinate sulfur–metal dative bond. The former compound exists as the noncovalently bonded

Subjects :: chemistry.chemical_classification
Structure analysis
Chemistry
Stereochemistry
Intermolecular force
chemistry.chemical_element
Medicinal chemistry
Inorganic Chemistry
Metal
Group (periodic table)
visual_art
visual_art.visual_art_medium
Dipolar bond
Non-covalent interactions
Alkyl
Indium

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