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Cyclized-polyacrylonitrile modified carbon nanofiber interlayers enabling strong trapping of polysulfides in lithium–sulfur batteries
- Source :
- Journal of Materials Chemistry A. 4:12973-12980
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- Lithium–sulfur (Li–S) batteries are seriously constrained by the diffusion and crossover of intermediary product polysulfides and their further reductions on the anode surface. Although carbon-based interlayers have been widely used to inhibit the detrimental shuttle effect in Li–S batteries, the weak physical adsorption of pure carbon materials for trapping polysulfides still leads to low recycle efficiency of active species and short cycle life for cells. Herein, we report a cyclized-polyacrylonitrile-cast carbon nanofiber (CP@CNF) film as an interlayer in Li–S batteries. By exploiting the CP@CNF interlayer, the batteries assembled with bare sulfur cathodes deliver superior rate capability and cycle stability. The reversible capacity could be maintained at 710 mA h g−1 after 200 cycles at 0.3C and a capacity of 560 mA h g−1 can be obtained even at a 2C rate. The improved performances are attributed to both the abundant pyridine groups in the cyclized polyacrylonitrile matrix, which can entrap polysulfides by strong interatomic attraction, and the three-dimensional porous conductive network composed of the carbon nanofiber skeleton and conjugated polymer matrix, giving rise to highly effective transfer pathways for electrons and ions.
- Subjects :
- chemistry.chemical_classification
Materials science
Renewable Energy, Sustainability and the Environment
Carbon nanofiber
Polyacrylonitrile
chemistry.chemical_element
Nanotechnology
02 engineering and technology
General Chemistry
Polymer
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Sulfur
0104 chemical sciences
Anode
chemistry.chemical_compound
Adsorption
chemistry
Chemical engineering
Nanofiber
General Materials Science
0210 nano-technology
Carbon
Subjects
Details
- ISSN :
- 20507496 and 20507488
- Volume :
- 4
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry A
- Accession number :
- edsair.doi...........4bee647a8128ed818abfd8b847c0a6bc