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Rational design of chiral stationary phases for capillary supercritical fluid chromatography

Authors :
Bryant E. Rossiter
Jerald S. Bradshaw
Milton L. Lee
Patrik Petersson
Masakatsu Eguchi
Karin E. Markides
Deborah F. Johnson
Source :
Tetrahedron Letters. 32:3609-3612
Publication Year :
1991
Publisher :
Elsevier BV, 1991.

Abstract

A new class of chiral copolymers consisting of chiral organic and dimethylsiloxane units is described. One example of such copolymers, containing alternating diamide and dimethylsiloxane units, has been synthesized. Using these chiral materials as stationary phases in capillary columns, chiral diols can be efficiently resolved by supercritical fluid chromatography.

Details

ISSN :
00404039
Volume :
32
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........4b9d76f6d273bccc08d09462b1f78444