The importance of lone pairs to structure and bonding of the novel germanium nitridophosphate GeP2N4

Authors :: Tristan de Boer
Cody Somers
Teak Boyko
Sebastian Ambach
Lucien Eisenburger
Wolfgang Schnick
Alexander Moewes
Source :: Journal of Materials Chemistry A. 11:6198-6204
Publication Year :: 2023
Publisher :: Royal Society of Chemistry (RSC), 2023.
Abstract: The new nitridophosphate GeP2N4 differs structurally from all other known MP2N4 phases, owing to a Ge2+ lone pair. Its stereochemical influence could be exploited to tune the properties of other compounds when M2+ is exchanged with Ge2+.

Subjects :: Renewable Energy, Sustainability and the Environment
General Materials Science
General Chemistry

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