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Hierarchically bimodal mesoporous silica fibers as building units for silica monolith with trimodal porous architecture
- Source :
- Ceramics International. 43:2174-2181
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- This work reports the controllable preparation of a unique kind of hierarchically mesoporous silica (HMS) fibers with bimodal porosities based on a simple TEOS/P123/HCl(aq.) templating system via the partitioned cooperative self-assembly (PCSA) process. Experimental results show that the formation of hierarchical mesostructures, especially the 2nd mode porous structure, depends on the interval time pertaining to the PCSA process. Synthetic conditions, including the interval time, temperature and stirring, are all found to be important in the evolution of fiber particle morphology. Moreover, such HMS fibers can be used as building units to prepare mesoporous silica monoliths with hierarchical trimodal pore systems via a simple gel-casting method, with additional (the 3rd modal) macropores originating from the packing of micron-sized HMS fibers. Such materials might further expand the application of both HMS fibers and HMS monoliths in various fields.
- Subjects :
- geography
geography.geographical_feature_category
Materials science
Process Chemistry and Technology
02 engineering and technology
Mesoporous silica
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Materials Chemistry
Ceramics and Composites
Particle
Fiber
Monolith
Composite material
B fibers
0210 nano-technology
Porosity
Subjects
Details
- ISSN :
- 02728842
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- Ceramics International
- Accession number :
- edsair.doi...........4b0aeee89b6f09e44087fb5a241b01cc