Catalytic Effect of Iron and Nickel on Gas Formation from Fast Biomass Pyrolysis in a Microfluidized Bed Reactor: A Kinetic Study

Isothermal pyrolysis of rice husk catalyzed by iron and nickel was conducted in a microfluidized bed reactor to investigate the forming characteristics and kinetics of the main gas components. Results indicated that both Fe and Ni showed a catalytic effect on the releasing behavior of gaseous products during rice husk pyrolysis. The forming reaction rate of H2 and CO2 was significantly promoted with the addition of Fe or Ni, while that of CH4 was inhibited. For CO, Ni showed a positive effect while Fe showed a negative effect on its forming rate. The char evolution of rice husk was also influenced by the presence of Fe and Ni from the SEM-EDX and BET results. The model fitting method was used to calculate the kinetics of gas releasing to further investigate the effect of Fe and Ni, and the most probable reaction mechanism was obtained based on the relative error between experimental and calculated conversion fraction. Corresponding to the changing trend of reaction rate, the obtained activation energies f...