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Synthesis and crystal structure of methyl 2-(2,4-dichloro-5-fluorobenzoyl)-3-(pyrimidin-2-ylamino)acrylate
- Source :
- Research on Chemical Intermediates. 38:2355-2363
- Publication Year :
- 2012
- Publisher :
- Springer Science and Business Media LLC, 2012.
-
Abstract
- Methyl 2-(2,4-dichloro-5-fluorobenzoyl)-3-(pyrimidin-2-ylamino)acrylate has been prepared. Its crystal structure is discussed. The compound crystallizes in the triclinic space group P-1 with a = 11.6259 (7) A, b = 11.8789 (7) A, c = 13.9206 (5) A, α = 68.0250 (10)°, β = 77.5660 (10)°, γ = 62.4950 (10)°, V = 1579.18 (14) A3, Z = 4. There are two independent but chemically identical molecules in the asymmetric unit. The molecules are packed in the crystal structure by weak intermolecular C–H···O and C–H···F interactions.
Details
- ISSN :
- 15685675 and 09226168
- Volume :
- 38
- Database :
- OpenAIRE
- Journal :
- Research on Chemical Intermediates
- Accession number :
- edsair.doi...........4a467aefa7fe3691e50ed1a46ed2bec9
- Full Text :
- https://doi.org/10.1007/s11164-012-0551-8