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Visible light induced formation of a tungsten hydride complex

Authors :
Diane P. Isaacs
Cole T. Gruninger
Tao Huang
Aldo M. Jordan
Genique Nicholas
Chun-Hsing Chen
Marc A. ter Horst
Jillian L. Dempsey
Source :
Dalton Transactions. 52:3210-3218
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

The bond cleavage of [CpW(CO)3]2 with blue light in the presence of acid leads to disproportionation followed by fast protonation. Quantum yield measurements indicate disproportionation occurs through a radical chain mechanism.

Subjects

Subjects :
Inorganic Chemistry

Details

ISSN :
14779234 and 14779226
Volume :
52
Database :
OpenAIRE
Journal :
Dalton Transactions
Accession number :
edsair.doi...........49fac511a3a1858fbca821531544815c