Measurements of the isobaric heat capacity of R1234yf in liquid phase at temperatures from 305K to 355K and pressures up to 5MPa

2,3,3,3-Tetrafluoropropene (R1234yf) is an environmentally friendly promising alternative to 1,1,1,2-tetrafluoroethane (R134a) in air conditioning applications. The heat capacity of R1234yf in liquid phase was investigated in this study. The measurements were carried out with a modified heat conduction calorimeter. A total of 74 data points were obtained among 305–355 K and 1.5–5 MPa. The uncertainty of the heat capacity measurements was estimated to be less than 1.7%. An empirical equation was correlated to reproduce the experimental result with its terms chosen by a stepwise method. The maximum deviation between the correlating equation and the experimental data was 1.5%. Furthermore, saturated liquid heat capacity of R1234yf was obtained by extrapolating the correlation to saturated pressures. Finally, a comparison was done between the present data and literature experimental data and calculations from a fundamental equation of state.