Triple Helical Ir(ppy) 3 Phenylene Cage Prepared by Diol‐Mediated Benzannulation: Synthesis, Resolution, Absolute Stereochemistry and Photophysical Properties

Cyclometalation of a triple helical N-doped phenylene cage prepared by ruthenium(0)-catalyzed diol-diene benzannulation delivers a chiral, conformationally constrained Ir(ppy)3 analogue. Like the parent complex, fac-Ir(ppy)3 , the iridium-containing PAH-cage is phosphorescent, but displays enhanced resistance to oxygen quenching.