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Recent theoretical and experimental advancements in the application of the van Oss–Chaudhury–Good acid–base theory to the analysis of polymer surfaces II. Some peculiar cases

Authors :
Stefano Siboni
C. Della Volpe
Mariano Anderle
Devid Maniglio
A. Lui
Cecilia Pederzolli
Giorgio Speranza
Roberto Canteri
Gloria Gottardi
Clara Cassinelli
Marco Morra
S. Janikowska
Source :
Journal of Adhesion Science and Technology. 17:1425-1456
Publication Year :
2003
Publisher :
Informa UK Limited, 2003.

Abstract

—According to the general guidelines presented in the accompanying paper, some relevant examples of common polymer surfaces are analysed and discussed; a number of polymers commercially available or laboratory synthesized have been analysed. In particular, the case of poly(vinyl chloride) (PVC), often considered as peculiar in the literature, is fully analysed on the basis of a new set of well-prepared samples, whose compositions were checked by high-vacuum spectroscopies. 'Equilibrium' contact angles, obtained by a new experimental technique, are presented. The results are, however, preliminary, because the final set of liquids used is not so 'well equilibrated' as possible, from the point of view of acid–base properties. The contact angle data obtained are analysed in a non-linear way to calculate the acid–base components of all the liquids and solids. The results are discussed and compared with those obtained from liquid–liquid interfaces presented in the accompanying paper. The physico-chemical featur...

Details

ISSN :
15685616 and 01694243
Volume :
17
Database :
OpenAIRE
Journal :
Journal of Adhesion Science and Technology
Accession number :
edsair.doi...........474a31f6c04410199aeea416d4f75631