Preparation and crystal structure of a two-co-ordinate manganese compound, bis[tris(trimethyl)silylmethyl]manganese

Authors :: Peter B. Hitchcock
J. David Smith
Alice C. Sullivan
Nabeel H. Buttrus
Colin Eaborn
Source :: Journal of the Chemical Society, Chemical Communications. :1380
Publication Year :: 1985
Publisher :: Royal Society of Chemistry (RSC), 1985.
Abstract: The product of the reaction between MnCl2 and tris(trimethylsilyl)methyl-lithium in 1:2 molar ratio in tetrahydrofuran is the monomeric species [Mn{C(SiMe3)3}2], the first two-co-ordinate manganese compound to be characterized.

Subjects :: Tris
Trimethylsilyl
Chemistry
Inorganic chemistry
chemistry.chemical_element
Manganese
Crystal structure
Medicinal chemistry
chemistry.chemical_compound
Monomer
X-ray crystallography
Molecular Medicine
Molecule
Tetrahydrofuran

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