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Preparation and formation mechanism of porous carbon nanosheets by thermal decomposition of polyvinyl alcohol films impregnated with zinc (II) and nitrate ions
- Source :
- Solid State Sciences. 65:33-40
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- Porous carbon nanosheets (PCNS) with high surface areas were prepared by thermal decomposition of polyvinyl alcohol (PVA) films impregnated with Zn 2+ and NO 3 − . Through this simple preparation method that required no additional activation processes, curved carbon nanosheets ( 2+ and NO 3 − indicated that the sheet-like structures originated from exothermic pyrolysis of NO 3 − associated with the thermal decomposition of PVA. According to the nitrogen adsorption isotherm analyses at 77 K, the PCNS had a high specific surface area (>1600 m 2 g -1 ) and bimodal pore structure consisting of micropores and mesopores. Because of their unique structural properties, the PCNS are attractive for use as electrode materials. The electrode performance of the PCNS was investigated in 1-M tetraethylammonium tetrafluoroborate ((C 2 H 5 ) 4 NBF 4 ) in propylene carbonate. The PCNS electrodes displayed high specific capacitance (86 F g -1 for cations and 115 F g -1 for anions). They also showed exceptionally high rate performance with ∼90% capacitance retention at current densities up to 2 A g -1 because their nanosheet structure allowed the rapid diffusion of ions inside the electrode.
- Subjects :
- Materials science
Inorganic chemistry
Thermal decomposition
chemistry.chemical_element
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
Polyvinyl alcohol
0104 chemical sciences
chemistry.chemical_compound
Adsorption
chemistry
Specific surface area
Propylene carbonate
General Materials Science
0210 nano-technology
Pyrolysis
Carbon
Nanosheet
Subjects
Details
- ISSN :
- 12932558
- Volume :
- 65
- Database :
- OpenAIRE
- Journal :
- Solid State Sciences
- Accession number :
- edsair.doi...........470cbadcc1abc3788eb26c62a9552955