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Hydroxy Acid-Assisted Synthesis of Highly Dispersed Ni-NiS on CdS as Effective Photocatalyst for Hydrogen Evolution
- Source :
- Catalysis Letters. 151:1707-1719
- Publication Year :
- 2020
- Publisher :
- Springer Science and Business Media LLC, 2020.
-
Abstract
- To achieve the well-dispersed Ni–NiS dual-cocatalysts anchored CdS, the samples have been successfully constructed by a cheap and convenient method of hydroxy acid assisted hydrothermal method. Based on the coordination and reduction effects of hydroxy acids, Ni2+ can be facilely transformed into the high dispersed dual-function sites of Ni0 electrons trap and NiS holes reservoir. The highly dispersed Ni–NiS dual-cocatalysts not only provide more dual-function active sites but also present distinctly enhanced visible light absorption, effectively separated electron hole pairs and quickly migrated charge carriers. The optimized Ni–NiS/CdS–CA presented an excellent photocatalytic H2 generation rate of 57.88 mmol·h−1·g−1, which is about 15.35 times higher than that of NiS/CdS. Moreover, the stability can be distinctly increased by modulating the surface cover of Ni–NiS with a suitable Ni/(Ni + Cd) atomic ratio. This work would provide a unique strategy to design the high effective photocatalysts with high dispersed bi-function dual cocatalysts. The well-dispersed Ni-NiS dual-cocatalysts anchored CdS in situ have been successfully constructed via the coordination and reduction effects of hydroxy acid assisted hydrothermal method. Ni-NiS/CdS-CA not only presents dual-function active sites but also exhibits distinctly enhanced visible light absorption, effectively separated electron hole pairs and quickly migrated charge carriers, resulting in a remarkable enhancement in photocatalytic H2 evolution activity.
- Subjects :
- 010405 organic chemistry
Chemistry
Carrier generation and recombination
General Chemistry
010402 general chemistry
Photochemistry
01 natural sciences
Catalysis
Hydrothermal circulation
0104 chemical sciences
Photocatalysis
Charge carrier
Atomic ratio
Absorption (electromagnetic radiation)
health care economics and organizations
Visible spectrum
Subjects
Details
- ISSN :
- 1572879X and 1011372X
- Volume :
- 151
- Database :
- OpenAIRE
- Journal :
- Catalysis Letters
- Accession number :
- edsair.doi...........4694d476ff2a96d2bb4afdb2c64a98fd