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Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading

Authors :
Sergei O. Kucheyev
Joseph M. Zaug
Peter J. Pauzauskie
Alex V. Hamza
Joe H. Satcher
Marcus A. Worsley
Theodore F. Baumann
Source :
Acta Materialia. 57:5131-5136
Publication Year :
2009
Publisher :
Elsevier BV, 2009.

Abstract

Here, we present the synthesis and characterization of low-density single-walled carbon nanotube-based aerogels (SWNT-CA). Aerogels with varying nanotube loading (0–55 wt.%) and density (20–350 mg cm −3 ) were fabricated and characterized by four-probe method, electron microscopy, Raman spectroscopy and nitrogen porosimetry. Several properties of the SWNT-CAs were highly dependent upon nanotube loading. At nanotube loadings of 55 wt.%, shrinkage of the aerogel monoliths during carbonization and drying was almost completely eliminated. Electrical conductivities are improved by an order of magnitude for the SWNT-CA (55 wt.% nanotubes) compared to those of foams without nanotubes. Surface areas as high as 184 m 2 g −1 were achieved for SWNT-CAs with greater than 20 wt.% nanotube loading.

Details

ISSN :
13596454
Volume :
57
Database :
OpenAIRE
Journal :
Acta Materialia
Accession number :
edsair.doi...........468759c1be121e66d14a68b1c4d40c2f