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Facile Synthesis of Lactones from Silyl ω-Siloxycarboxylates Usingp-Trifluoromethylbenzoic Anhydride and a Catalytic Amount of Active Lewis Acid

Authors :
Teruaki Mukaiyama
Isamu Shiina
Mitsutomo Miyashita
Jun Izumi
Source :
Chemistry Letters. 22:907-910
Publication Year :
1993
Publisher :
The Chemical Society of Japan, 1993.

Abstract

The lactonization of silyl ω-siloxycarboxylates is successfully carried out under mild conditions in good to high yields by using p-trifluoromethylbenzoic anhydride and a catalytic amount of active acidic species generated in situ from TiCl4 and AgClO4.

Details

ISSN :
13480715 and 03667022
Volume :
22
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........45341b753f3dc2f082ab118ea6111f21
Full Text :
https://doi.org/10.1246/cl.1993.907